Patterned layer design for group III nitride layer growth

ABSTRACT

A device having a layer with a patterned surface for improving the growth of semiconductor layers, such as group III nitride-based semiconductor layers with a high concentration of aluminum, is provided. The patterned surface can include a substantially flat top surface and a plurality of stress reducing regions, such as openings. The substantially flat top surface can have a root mean square roughness less than approximately 0.5 nanometers, and the stress reducing regions can have a characteristic size between approximately 0.1 microns and approximately five microns and a depth of at least 0.2 microns. A layer of group-III nitride material can be grown on the first layer and have a thickness at least twice the characteristic size of the stress reducing regions.

REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No.13/647,885, filed on 9 Oct. 2012, which claims the benefit of U.S.Provisional Application No. 61/545,261, which was filed on 10 Oct. 2011,and U.S. Provisional Application No. 61/556,160, which was filed on 4Nov. 2011, each of which is hereby incorporated by reference.

GOVERNMENT LICENSE RIGHTS

This invention was made with Federal government support under ContractNo. W911 NF-10-2-0023 awarded by Defense Advanced Research ProjectsAgency (DARPA). The government has certain rights in the invention.

TECHNICAL FIELD

The disclosure relates generally to semiconductor devices, and moreparticularly, to a design of a patterned substrate for layer growth,e.g., group III-nitride layer and emitting device growth.

BACKGROUND ART

For light emitting devices, such as light emitting diodes (LEDs), andespecially deep ultraviolet light emitting diodes (DUV LEDs), minimizinga dislocation density in the semiconductor layers increases theefficiency of the device. To this extent, several approaches have soughtto grow dislocation free semiconductor layers on patterned substrates.Some approaches have proposed various patterning of the underlyingsubstrate. For example, FIGS. 1 and 2 show uses of an overgrowingtechnique according to the prior art. The technique of FIG. 1 usespatterning of convex protrusions on the underlying substrate andovergrowing a gallium nitride (GaN) semiconductor layer. In the approachof FIG. 2, buildup of semiconductor material in patterned depressions isallowed. A reduction of dislocations may result due to an overallreduction of stress in the semiconductor layer. Another approach usespatterned nanopillars to reduce stress of an epitaxial layer.

Other approaches have used microchannel epitaxy (MCE). FIG. 3 shows anillustration of microchannel epitaxy according to the prior art. Inthese approaches, a narrow channel is used as a nucleation centercontaining low defect information from the substrate. An opening in amask acts as a microchannel, which transfers crystal information to theovergrown layer, while the mask prevents dislocations from transferringto the overgrown layer. As a result, the overgrown layer can becomedislocation free. The three-dimensional structure of the MCE alsoprovides another advantage to stress release. The residual stress can bereleased effectively since the overgrown layer easily deforms. Inanother approach, a mask is applied at a location of a largeconcentration of dislocation densities to block their furtherpropagation.

Another approach for controlling dislocations in aluminum nitride (AlN)and aluminum gallium nitride (AlGaN) layers first places seeds includingdotted masks on the substrate or a template layer, and then grows theAlN or AlGaN layer over the substrate. The dislocations are attractedtowards the center of the seeds and are accumulated there, therebyreducing the dislocation density at other portions of the layers.

SUMMARY OF THE INVENTION

Aspects of the invention provide a device having a layer with apatterned surface for improving the growth of semiconductor layers, suchas group III nitride-based semiconductor layers with a highconcentration of aluminum. The patterned surface can include asubstantially flat top surface and a plurality of stress reducingregions, such as openings. The substantially flat top surface can have aroot mean square roughness less than approximately 0.5 nanometers, andthe stress reducing regions can have a characteristic size betweenapproximately 0.1 microns and approximately five microns and a depth ofat least 0.2 microns. A layer of group-III nitride material can be grownon the first layer and have a thickness at least twice thecharacteristic size of the stress reducing regions.

A first aspect of the invention provides a device comprising: a firstlayer having a patterned surface, wherein the patterned surface includesa top surface having a root mean square roughness less thanapproximately 0.5 nanometers and a plurality of openings in the topsurface, wherein each of the plurality of openings has a characteristicsize between approximately 0.1 microns and approximately five micronsand a depth of at least 0.2 microns; and a second layer directly on thepatterned surface of the first layer, wherein the second layer is agroup III-nitride material having an aluminum concentration of at leastseventy percent and having a thickness at least twice the characteristicsize of the openings.

A second aspect of the invention provides a light emitting devicecomprising: a substrate having a patterned surface, wherein thepatterned surface includes a top surface having a root mean squareroughness less than approximately 0.5 nanometers and a plurality ofopenings formed in the top surface, wherein each of the plurality ofopenings has a characteristic size between approximately 0.1 microns andapproximately five microns and a depth of at least 0.2 microns; and asecond layer directly on the substrate, wherein the second layer is agroup III-nitride material having an aluminum concentration of at leastseventy percent and having a thickness at least twice the characteristicsize of the openings.

A third aspect of the invention provides a device comprising: a firstlayer having a patterned surface, wherein the patterned surface includesa top surface having a root mean square roughness less thanapproximately 0.5 nanometers and a first plurality of stress reducingregions on the top surface, wherein each of the first plurality ofstress reducing regions has a characteristic size between approximately0.1 microns and approximately five microns and wherein the firstplurality of stress reducing regions are separated by a distance lessthan or equal to the characteristic size; and a second layer directly onthe patterned surface of the first layer, wherein the second layer is agroup III-nitride material having an aluminum concentration of at leastseventy percent and having a thickness at least twice the characteristicsize of the openings.

The illustrative aspects of the invention are designed to solve one ormore of the problems herein described and/or one or more other problemsnot discussed.

BRIEF DESCRIPTION OF THE DRAWINGS

These and other features of the disclosure will be more readilyunderstood from the following detailed description of the variousaspects of the invention taken in conjunction with the accompanyingdrawings that depict various aspects of the invention.

FIG. 1 shows use of an overgrowing technique according to the prior art.

FIG. 2 shows another use of an overgrowing technique according to theprior art.

FIG. 3 shows an illustration of microchannel epitaxy according to theprior art.

FIG. 4 shows a schematic structure of an illustrative emitting deviceaccording to an embodiment.

FIG. 5 shows a schematic structure of an illustrative heterostructurefield effect transistor (HFET) according to an embodiment.

FIGS. 6A and 6B show illustrative patterned surfaces according toembodiments.

FIGS. 7A and 7B show illustrative material coalescence patterns forgrowth using different patterning lattices over a patterned substrateaccording to an embodiment.

FIGS. 8A and 8B show illustrative material coalescence patterns forgrowth over the patterned substrates shown in FIGS. 6A and 6B,respectively, according to an embodiment.

FIG. 9 shows an atomic force microscope (AFM) scan of an AlN or AlGaNlayer grown on the patterned substrate of FIG. 6B according to anembodiment.

FIG. 10 shows an illustrative cross section of AlN material growth overa patterned substrate according to an embodiment.

FIGS. 11A and 11B show schematic diagrams illustrating a multistepformation procedure according to embodiments.

FIG. 12 shows a top view of an illustrative layer formed using multiplesub-layers according to an embodiment.

FIG. 13 shows a schematic diagram of an illustrative multistep layerformation according to another embodiment.

FIG. 14 shows a top view of an illustrative patterned surface of asubstrate according to an embodiment.

FIG. 15 shows an illustrative patterned surface according to anembodiment.

FIG. 16 shows an illustrative flow diagram for fabricating a circuitaccording to an embodiment.

It is noted that the drawings may not be to scale. The drawings areintended to depict only typical aspects of the invention, and thereforeshould not be considered as limiting the scope of the invention. In thedrawings, like numbering represents like elements between the drawings.

DETAILED DESCRIPTION OF THE INVENTION

As indicated above, aspects of the invention provide a device having alayer with a patterned surface for improving the growth of semiconductorlayers, such as group III nitride-based semiconductor layers with a highconcentration of aluminum. The patterned surface can include asubstantially flat top surface and a plurality of stress reducingregions, such as openings. The substantially flat top surface can have aroot mean square roughness less than approximately 0.5 nanometers, andthe stress reducing regions can have a characteristic size betweenapproximately 0.1 microns and approximately five microns and a depth ofat least 0.2 microns. A layer of group-III nitride material can be grownon the first layer and have a thickness at least twice thecharacteristic size of the stress reducing regions. As used herein,unless otherwise noted, the term “set” means one or more (i.e., at leastone) and the phrase “any solution” means any now known or laterdeveloped solution.

Turning to the drawings, FIG. 4 shows a schematic structure of anillustrative emitting device 10 according to an embodiment. In a moreparticular embodiment, the emitting device 10 is configured to operateas a light emitting diode (LED), such as a conventional or superluminescent LED. Alternatively, the emitting device 10 can be configuredto operate as a laser diode (LD). In either case, during operation ofthe emitting device 10, application of a bias comparable to the band gapresults in the emission of electromagnetic radiation from an activeregion 18 of the emitting device 10. The electromagnetic radiationemitted by the emitting device 10 can comprise a peak wavelength withinany range of wavelengths, including visible light, ultravioletradiation, deep ultraviolet radiation, infrared light, and/or the like.

The emitting device 10 includes a heterostructure comprising a substrate12, a buffer layer 14 adjacent to the substrate 12, an n-type claddinglayer 16 (e.g., an electron supply layer) adjacent to the buffer layer14, and an active region 18 having an n-type side 19A adjacent to then-type cladding layer 16. Furthermore, the heterostructure of theemitting device 10 includes a p-type layer 20 (e.g., an electronblocking layer) adjacent to a p-type side 19B of the active region 18and a p-type cladding layer 22 (e.g., a hole supply layer) adjacent tothe p-type layer 20.

In a more particular illustrative embodiment, the emitting device 10 isa group III-V materials based device, in which some or all of thevarious layers are formed of elements selected from the group III-Vmaterials system. In a still more particular illustrative embodiment,the various layers of the emitting device 10 are formed of group IIInitride based materials. Group III nitride materials comprise one ormore group III elements (e.g., boron (B), aluminum (Al), gallium (Ga),and indium (In)) and nitrogen (N), such that B_(W)Al_(X)Ga_(Y)In_(Z)N,where 0≦W, X, Y, Z≦1, and W+X+Y+Z=1. Illustrative group III nitridematerials include AlN, GaN, InN, BN, AlGaN, AlInN, AlBN, AlGaInN,AlGaBN, AlInBN, and AlGaInBN with any molar fraction of group IIIelements.

An illustrative embodiment of a group III nitride based emitting device10 includes an active region 18 (e.g., a series of alternating quantumwells and barriers) composed of In_(y)Al_(x)Ga_(1−x−y)N,Ga_(z)In_(y)Al_(x)B_(1−x−y−z)N, an Al_(x)Ga_(1−x)N semiconductor alloy,or the like. Similarly, both the n-type cladding layer 16 and the p-typelayer 20 can be composed of an In_(y)Al_(x)Ga_(1−x−y)N alloy, aGa_(z)In_(y)Al_(x)B_(1−x−y−z)N alloy, or the like. The molar fractionsgiven by x, y, and z can vary between the various layers 16, 18, and 20.The substrate 12 can be sapphire, silicon (Si), germanium, siliconcarbide (SiC), a bulk semiconductor template material, such as AlN, GaN,BN, AlGaN, AlInN, AlON, LiGaO₂, AlGaBN, AlGaInN, AlGaInBN, and/or thelike, or another suitable material, and can be polar, non-polar, orsemi-polar. The buffer layer 14 can be composed of AlN, AlGaN, AlInN,AlGaBN, AlGaInN, AlGaInBN, an AlGaN/AlN superlattice, and/or the like.

As shown with respect to the emitting device 10, a p-type metal 24 canbe attached to the p-type cladding layer 22 and a p-type contact 26 canbe attached to the p-type metal 24. Similarly, an n-type metal 28 can beattached to the n-type cladding layer 16 and an n-type contact 30 can beattached to the n-type metal 28. The p-type metal 24 and the n-typemetal 28 can form ohmic contacts to the corresponding layers 22, 16,respectively. In an embodiment, the p-type metal 24 and the n-type metal28 each comprise several conductive and reflective metal layers, whilethe n-type contact 30 and the p-type contact 26 each comprise highlyconductive metal. In an embodiment, the p-type cladding layer 22 and/orthe p-type contact 26 can be at least partially transparent (e.g.,semi-transparent or transparent) to the electromagnetic radiationgenerated by the active region 18. For example, the p-type claddinglayer 22 and/or the p-type contact 26 can comprise a short periodsuperlattice lattice structure, such as an at least partiallytransparent magnesium (Mg)-doped AlGaN/AlGaN short period superlatticestructure (SPSL). Furthermore, the p-type contact 26 and/or the n-typecontact 30 can be at least partially reflective of the electromagneticradiation generated by the active region 18. In another embodiment, then-type cladding layer 16 and/or the n-type contact 30 can be formed of ashort period superlattice, such as an AlGaN SPSL, which is at leastpartially transparent to the electromagnetic radiation generated by theactive region 18.

As used herein, a layer is at least partially transparent when the layerallows at least a portion of electromagnetic radiation in acorresponding range of radiation wavelengths to pass there through. Forexample, a layer can be configured to be at least partially transparentto a range of radiation wavelengths corresponding to a peak emissionwavelength for the light (such as ultraviolet light or deep ultravioletlight) emitted by the active region 18 (e.g., peak emissionwavelength+/−five nanometers). As used herein, a layer is at leastpartially transparent to radiation if it allows more than approximately0.5 percent of the radiation to pass there through. In a more particularembodiment, an at least partially transparent layer is configured toallow more than approximately five percent of the radiation to passthere through. In a still more particular embodiment, an at leastpartially transparent layer is configured to allow more thanapproximately ten percent of the radiation to pass there through.Similarly, a layer is at least partially reflective when the layerreflects at least a portion of the relevant electromagnetic radiation(e.g., light having wavelengths close to the peak emission of the activeregion). In an embodiment, an at least partially reflective layer isconfigured to reflect at least approximately five percent of theradiation.

As further shown with respect to the emitting device 10, the device 10can be mounted to a submount 36 via the contacts 26, 30. In this case,the substrate 12 is located on the top of the emitting device 10. Tothis extent, the p-type contact 26 and the n-type contact 30 can both beattached to a submount 36 via contact pads 32, 34, respectively. Thesubmount 36 can be formed of aluminum nitride (AlN), silicon carbide(SiC), and/or the like.

Any of the various layers of the emitting device 10 can comprise asubstantially uniform composition or a graded composition. For example,a layer can comprise a graded composition at a heterointerface withanother layer. In an embodiment, the p-type layer 20 comprises a p-typeblocking layer having a graded composition. The graded composition(s)can be included to, for example, reduce stress, improve carrierinjection, and/or the like. Similarly, a layer can comprise asuperlattice including a plurality of periods, which can be configuredto reduce stress, and/or the like. In this case, the composition and/orwidth of each period can vary periodically or aperiodically from periodto period.

It is understood that the layer configuration of the emitting device 10described herein is only illustrative. To this extent, an emittingdevice/heterostructure can include an alternative layer configuration,one or more additional layers, and/or the like. As a result, while thevarious layers are shown immediately adjacent to one another (e.g.,contacting one another), it is understood that one or more intermediatelayers can be present in an emitting device/heterostructure. Forexample, an illustrative emitting device/heterostructure can include anundoped layer between the active region 18 and one or both of the p-typecladding layer 22 and the n-type cladding layer 16.

Furthermore, an emitting device/heterostructure can include aDistributive Bragg Reflector (DBR) structure, which can be configured toreflect light of particular wavelength(s), such as those emitted by theactive region 18, thereby enhancing the output power of thedevice/heterostructure. For example, the DBR structure can be locatedbetween the p-type cladding layer 22 and the active region 18.Similarly, a device/heterostructure can include a p-type layer locatedbetween the p-type cladding layer 22 and the active region 18. The DBRstructure and/or the p-type layer can comprise any composition based ona desired wavelength of the light generated by thedevice/heterostructure. In one embodiment, the DBR structure comprises aMg, Mn, Be, or Mg+Si-doped p-type composition. The p-type layer cancomprise a p-type AlGaN, AlInGaN, and/or the like. It is understood thata device/heterostructure can include both the DBR structure and thep-type layer (which can be located between the DBR structure and thep-type cladding layer 22) or can include only one of the DBR structureor the p-type layer. In an embodiment, the p-type layer can be includedin the device/heterostructure in place of an electron blocking layer. Inanother embodiment, the p-type layer can be included between the p-typecladding layer 22 and the electron blocking layer.

FIG. 5 shows a schematic structure of an illustrative heterostructurefield effect transistor (HFET) 50 according to an embodiment. Asillustrated, the HFET 50 can comprise a substrate 12, a buffer layer 14formed thereon, an active layer 52 formed on the buffer layer 14, and abarrier layer 54 formed on the active layer 52. Additionally, the HFET50 is shown including a gate passivation layer 56, on which a gate 58 islocated, a source electrode 60, and a drain electrode 62. Duringoperation of the HFET 50, the gate 58 can be used to control the flow ofcurrent along a device channel formed by the active layer 52 between thesource electrode 60 and the drain electrode 62 using any solution.

In an embodiment, the HFET 50 is a group III-V materials based device,in which some or all of the various layers 14, 52, 54 are formed ofelements selected from the group III-V materials system. In a moreparticular illustrative embodiment, the various layers of the HFET 50are formed of group III nitride based materials as described herein. Tothis extent, the substrate 12 and the buffer layer 14 can be configuredas described herein. In a still more particular illustrative embodiment,the active layer 52 is formed of GaN, and the barrier layer 54 is formedof AlInGaN. The gate passivation layer 56 can be formed of any type ofdielectric material, such as silicon nitride (Si₃N₄), or the like. Eachof the electrodes 62, 64 and the gate 58 can be formed of a metal.

While a light emitting device 10 (FIG. 4) and a HFET 50 are shown, it isunderstood that aspects of the invention can be utilized in theformation of any type of device. For example, the device can be a lightdetecting device, a photodetector, and/or the like. Similarly, whileaspects of the invention are shown and described with respect to growthof a layer on a substrate 12, it is understood that any junction betweentwo layers in a device heterostructure can include a patterned surface40 as described herein. Additionally, aspects of the invention can beapplied to the manufacture of non-electronic devices. For example,aspects of the invention can be used in the manufacture of an opticaldevice such as a lens.

Regardless, as illustrated in FIGS. 4 and 5, each device 10, 50 caninclude a substrate 12 having a patterned surface 40. The patternedsurface 40 can be configured to: provide for relaxation of stressbuildup between the substrate 12 and an adjacent layer, such as thebuffer layer 14; yield a semiconductor layer, such as the buffer layer14, having a lower density of dislocations; and/or the like. To thisextent, the patterned surface 40 can enable the growth of a singlecrystal semiconductor layer thereon.

The patterned surface 40 can be specifically configured to grow AlN andAlGaN semiconductor layers with an aluminum concentration higher thanapproximately seventy percent. In an embodiment, the buffer layer 14 isformed of AlN and/or AlGaN, and has an aluminum concentration higherthan approximately seventy percent. The patterned surface 40 cancomprise a set of top surfaces, such as the top surface 42, and aplurality of openings 44, which disrupt a continuity of the set of topsurfaces 42. As described herein, each of the set of top surfaces 42 canbe substantially flat, which can be configured to provide a set ofepi-ready (e.g., ready for epilayer growth) top surfaces 42 for growthof the buffer layer 14. For example, for a substrate 12 formed ofsapphire and a buffer layer 14 formed of aluminum nitride, the set oftop surfaces 42 can have a root mean square roughness that is less thanapproximately 0.5 nanometers.

FIGS. 6A and 6B show illustrative patterned surfaces 40A, 40B accordingto embodiments. In FIG. 6A, the patterned surface 40A is formed by aplurality of protruding regions, such as the region 46, and a pluralityof openings 44 between the protruding regions 46. Each protruding region46 can have a substantially flat top surface 42 (e.g., a root meanroughness less than approximately 0.5 nanometers). As used herein, thetop surface 42 of a protruding region 46 refers to the surface of theregion 46 that is furthest from the substrate 12 and on which anadjacent layer will be formed. In an embodiment, a characteristic size(e.g., diameter) of the plurality of protruding regions 46 is betweenapproximately 0.1 microns and approximately 5.0 microns. Furthermore, acharacteristic size of the plurality of openings 44 between theplurality of protruding regions 46 can have a size less than or equal tothe characteristic size of the plurality of protruding regions 46.

In FIG. 6B, the patterned surface 40B is formed by a plurality ofopenings 44 (e.g., depressions) present in a top surface 42 of thesubstrate 12. Each opening 44 can have a substantially vertical wall anda substantially flat bottom surface. For example, the bottom surface ofthe openings 44 and/or the top surface 42 of the substrate can have aroot mean square roughness that is less than approximately 0.5nanometers. In an embodiment, a characteristic size (e.g., diameter) ofthe openings 44 is between approximately 0.1 microns and approximatelyfive microns. Furthermore, the openings 44 can be spaced from oneanother by gaps having a size less than approximately twice a diameterof the openings 44. In a more particular embodiment, the gaps have sizesless than approximately a diameter of the openings. In an embodiment,the openings 44 can have substantially circular cross sections and beformed in a lateral hexagonal pattern. However, it is understood thatthe openings 44 can comprise any combination of one or more of varioustypes/shapes of cross-sectional patterns and form any type of pattern.

The patterned surfaces 40A, 40B can be formed using any solution. Forexample, for a substrate 12 formed of sapphire, AlN, or the like, thepatterned surfaces 40A, 40B can be formed using a combination oflithography and etching. In an embodiment, the patterned surfaces 40A,40B are formed using photolithography and wet chemical etching. However,it is understood that other types of lithography, such as e-beam,stepper, and/or the like, and/or other types of etching, such as dryetching, can be used.

During fabrication of a device 10 (FIG. 4), 50 (FIG. 5), a semiconductorlayer, such as the buffer layer 14 (FIGS. 4 and 5), can be formeddirectly on the patterned surface 40 of the substrate 12. As describedherein, the buffer layer 14 can have a high aluminum content (e.g.,greater than seventy percent). For optimized growth conditions of AlN,Al_(x)Ga_(1−x)N with a high value for x (e.g., greater than 0.7), andthe like, the material has a much lower ratio of lateral to verticalgrowth rates (1:2) as compared to GaN (>>1:1). As a result, to achievelateral growth of AlN of one micron, the layer thickness must beincreased by at least two microns. This leads to significant stressaccumulation and wing tilt of the laterally overgrown material, which,in turn, causes the generation of defects (e.g., dislocations) aftercoalescence.

FIGS. 7A and 7B show illustrative material coalescence patterns 70A, 70Bfor growth using different patterning lattices over a patternedsubstrate according to an embodiment. In each case, the material cancomprise AlN or AlGaN and the patterned substrate is formed using theconvex protruding regions 46 as shown in FIG. 6A. In the materialcoalescence pattern 70A, coalescence starts at the corners ofneighboring hexagons (indicated by circles), which creates boundariesfor possible stress relaxation through the generation of dislocations orcracks. In the material coalescence pattern 70B, coalescence occursalong the sides of the neighboring hexagons, where stress relaxation canoccur through the generation of dislocations or cracks.

FIGS. 8A and 8B show illustrative material coalescence patterns 72A, 72Bfor growth over the patterned substrates 40A, 40B shown in FIGS. 6A and6B, respectively, according to an embodiment. In each case, the materialbeing grown can comprise AlN, AlGaN, or the like. As discussed herein,for growth over the patterned substrate 40A, the material coalescencepattern 72A includes various locations where dislocations and/or crackscan form. In contrast, for growth over the patterned substrate 40B, amajority of the surface can be flat, which is particularly suitable forepitaxial growth of AlN or AlGaN. As a result, the use of the patternedsubstrate 40B for the growth of these materials results in coalescencetaking place primarily in a single point, thereby reducing an effect ofdislocation regeneration and relaxation/cracking.

To this extent, the use of the patterned substrate 40B can provide abetter surface for promoting the coalescence of laterally grown AlN andAlGaN than use of the patterned substrate 40A. In particular, thepatterned surface 40B can include small features (e.g., concavedepressions) and a dense pattern to promote coalescence of laterallygrown AlN, AlGaN, and/or the like. FIG. 9 shows an atomic forcemicroscope (AFM) scan of an AlN or AlGaN layer grown on the patternedsubstrate 40B according to an embodiment. The dots (some of which arecircled in the figure) on the AFM scan indicate locations where thecoalescence of dislocations has been achieved. The AFM root mean square(RMS) for the coalescence of the layer is less than 0.2 nanometers.

FIG. 10 shows an illustrative cross section of AlN material 74 growthover a patterned substrate 40 according to an embodiment. Asillustrated, the patterned substrate 40 includes a plurality of openings44, each of which can include a mask 76 located on a bottom surfacethereof. The patterned substrate 40 can be formed using a compositesubstrate 12. For example, the substrate 12 can include a layer of afirst material 12A, such as sapphire or the like, on which a templatelayer 12B including the various openings 44 formed therein is formed.The template layer 12B can comprise any type of suitable material for agrowth initiation layer, such as AlN, AlGaN, or the like. The mask 76can be any amorphous or polycrystalline material, including but notlimited to silicon dioxide, silicon nitride, and the like. During growthof the AlN material 74, some polycrystalline material 78, can grow inthe openings 44. The mask 76 can be configured to promote such growth.However, the openings 44 can be configured such that the overgrowth ofthe AlN material 74 occurs prior to the openings 44 filling with thepolycrystalline material 78. In an embodiment, the openings 44 can havea diameter that is less than one half of a thickness of thesemiconductor layer of material 74 being grown thereon. Furthermore, theopenings 44 can have a depth of at least 0.2 microns.

In an embodiment, one or more layers of the heterostructure can beformed using a multistep patterning and growing, e.g., epitaxy/etch,procedure. The multistep formation procedure can enable dislocations tobe filtered out as the layer is grown. For example, FIGS. 11A and 11Bshow schematic diagrams 80A, 80B illustrating a multistep formationprocedure according to embodiments. In the diagram 80A, the substrate 12includes a single layer of material (e.g., sapphire, AlGaN buffer,and/or the like), which has a patterned surface 40. In the diagram 80B,a composite substrate 12 is used, which includes a layer of a firstmaterial 12A (e.g., sapphire, AlGaN, and/or the like), and a templatelayer 12B formed thereon, which includes a pattern of openings 44 asdescribed herein to form the patterned surface 40.

In either case, a first sub-layer 14A can be grown over the patternedsurface 40. The sub-layer 14A can include one or more high dislocationregions 82, one or more dislocations 84 due to coalescence of adjacentregions, and/or the like. After growing the first sub-layer 14A, a topsurface of the sub-layer 14A can be patterned with a set of stressreducing regions, such as a second plurality of openings 86. Theopenings 86 can be formed such that the openings 86 are verticallyoffset from the openings 44 in the patterned surface 40. For example,the openings 86 and the openings 44 can form a vertical checkerboardarrangement. In this manner, the growth of a layer can include multiplelevels of openings, where adjacent levels of openings are verticallyshifted with respect to one another. In an embodiment, each level ofopenings is formed using a mask, which is vertically shifted withrespect to the underlying layer forming a periodic structure with atleast two sub-layers 14A, 14B.

In an embodiment, multiple patterns can be used in forming a layer(e.g., a unique pattern for each sub-layer 14A, 14B). The patterns canform any of two Bravais lattices, which can form either multilayerBravais structures, polytypes, or the like, where symmetry and/orperiods can change from one sub-layer to the next. FIG. 12 shows a topview of an illustrative layer 88 formed using multiple sub-layersaccording to an embodiment. The layer 88 can be formed of an AlN/AlGaNmaterial using a multistep patterning and growing, e.g., epitaxy/etch,procedure and a close packed patterning lattice. Additionally, eachlevel can include a pattern of openings having a lateral hexagonalarrangement. As illustrated, such a lattice enables placement of thepatterned openings for one level to be located between the patternedopenings of a previous level and formation of an overall hexagonalclose-packed three dimensional arrangement.

While aspects of the invention have been primarily described withrespect to the use of openings to provide a roughening pattern forrelaxation of stress buildup, a lower density of dislocations, and/orthe like, it is understood that alternative solutions can be used toprovide stress reducing regions. To this extent, FIG. 13 shows aschematic diagram of an illustrative multistep layer formation accordingto another embodiment. In this case, the roughening pattern includes aset of masks 92A, which are formed on the buffer layer 14 prior togrowth of a first sub-layer 90A. The masks 92A enable the growth of lowdislocation regions in the regions of the sub-layer 90A located abovethe masks 92A. After growth of the sub-layer 90A, a second set of masks92B are formed thereon, and a second sub-layer 90B is grown. Asillustrated, the second set of masks 92B can be vertically offset fromthe first set of masks 92A, and can block high dislocation regions,which can form between the masks 92A, from further verticallypropagating. Similarly, a third set of masks 92C can be formed on thesecond sub-layer 90B and a third sub-layer 90C can be grown thereon. Ascan be seen, a number of dislocations within the sub-layer 90C can besubstantially lower than a number of dislocations present in the lowestsub-layer 90A.

The substrate 12 can be sapphire, the buffer layer 14 can be AlN, AlGaN,or the like, and each of the sub-layers 90A-90C can be formed of AlN,GaN, AlGaN, or the like. The masks 92A-92C can be formed of any materialhaving a low affinity for aluminum adatoms. For example, the masks92A-92C can be formed of carbon or a carbon based material, such asgraphite, graphene, nanocrystalline diamond, or the like. While threesub-layers 90A-90C are shown, it is understood that any number ofsub-layers 90A-90C can be grown. Furthermore, while the sets of masks92A-92C are shown including two alternating patterns of masks, it isunderstood that any number of mask patterns can be used to form aperiodic pattern of any number of dimensions (e.g., one, two, or three).While the multistep patterning process is shown and described inconjunction with growing a single layer of a heterostructure, it isunderstood that the process can be used to grow multiple layers of theheterostructure. For example, each sub-layer can be a distinct layer ofthe heterostructure rather than a portion of a layer.

In an embodiment, a surface of a substrate 12 can include multiplepatterns. For example, FIG. 14 shows a top view of an illustrativepatterned surface of a substrate 12 according to an embodiment. In thiscase, the substrate 12 includes a plurality of stripes, such as stripes94A and 94B, of an isolating material. The isolating material cancomprise silicon dioxide, silicon nitride, a carbon based material, orany amorphous or polycrystalline material. As illustrated, the stripes94A, 94B can form a plurality of regions, such as regions 96A and 96B,each of which is isolated from another region by the stripes 94A, 94B.Each region 96A, 96B can comprise a patterned surface configured asdescribed herein. Furthermore, the plurality of regions 96A, 96B caninclude patterned surfaces formed using a different solution and/orhaving different attributes. In this manner, each region 96A, 96B cancomprise a configuration, which is suitable for stress reduction throughlateral epitaxial overgrowth, selective area growth, selectivepolycrystalline growth, and/or the like.

In an embodiment, one or more aspects of the pattern are configuredbased on radiation desired to pass through the corresponding interface.For example, a characteristic size of the pattern, a distance betweenthe patterning regions (e.g., openings or masks), a depth of the pattern(e.g., opening or mask depth), and/or the like, can be selected based ona target wavelength of the radiation. In an embodiment, the distancebetween adjacent masks or openings can be greater than the targetwavelength. Furthermore, a characteristic size of the opening or maskcan be in a range from approximately 0.25 times to approximately fivetimes the distance between adjacent masks or openings. The targetwavelength can be selected based on a peak wavelength of radiationdesired to pass through the patterned surface(s) during operation of adevice, such as the device 10 (FIG. 4), and can be within any range ofwavelengths, including visible light, ultraviolet radiation, deepultraviolet radiation, infrared light, and/or the like. In anembodiment, the target wavelength corresponds to the peak wavelength ofthe radiation generated in the active region 18 (FIG. 4) of the device10.

Furthermore, one or more patterned surfaces described herein can beconfigured to form a photonic crystal in the lateral and/or verticaldirections of a heterostructure. Additionally, a patterned surfacedescribed herein can be configured to increase a scattering of diffusivelight between the substrate and a semiconductor layer or betweenadjacent semiconductor layers. Similarly, one or more attributes of apattern, such as a density of the openings/masks, a characteristic size,and/or the like, can vary laterally or between patterns spacedvertically to provide, for example, a gradient in an effectiverefractive index of the resulting layer(s), control of the refractiveindex, manipulate the deflection of radiation passing through thestructure, and/or the like.

For example, FIG. 15 shows an illustrative patterned surface 40Caccording to an embodiment. In this case, the patterned surface 40Cincludes two distinct scales. In particular, a set of large scaleopenings 44A (e.g., micron size openings) can be included and configuredto improve a quality of the semiconductor layers grown over thepatterned surface 40C, e.g., by reducing a number of dislocationspresent in the semiconductor layers. Furthermore, a set of small scaleopenings 44B (e.g., nano size openings such as in a range betweenapproximately 40-150 nanometers) can be included and configured based onat least one light propagation property for the device, e.g., to improveand/or adjust one or more attributes of light propagation (e.g.,extraction) to/from the semiconductor layers. To this extent, the smallscale openings 44B can be formed in a periodic structure. Additionally,the small scale openings 44B can comprise lattice constants in lateraland/or vertical directions that are different than the lattice constantscorresponding to the large scale openings 44A. In an embodiment, the setof large scale openings 44A has a periodic pattern defined by a Bravaisset of lattice constants L1 and the set of small scale openings 44B hasa periodic pattern defined by a Bravais set of lattice constants L2,where at least some elements of the set L2 are different from thecorresponding elements of the set L1. Alternatively, the large scaleopenings 44A and/or the small scale openings 44B can be aperiodic.

Returning to FIGS. 4 and 5, it is understood that a device 10, 50, or aheterostructure used in forming a device 10, 50, including one or morepatterned surfaces 40 as described herein, can be fabricated using anysolution. For example, a device/heterostructure can be manufactured byobtaining (e.g., forming, preparing, acquiring, and/or the like) asubstrate 12, forming the patterned surface 40 of the substrate (e.g.,by etching, growing a template layer, and/or the like), and forming(e.g., growing) another layer thereon. In an embodiment, the growth ofone or more layers of the heterostructure includes periodic growth ofself-assembly structures on a patterned surface. The growth of suchstructures can be implemented by varying one or more growth conditions(e.g., a growth temperature), a ratio of elements (e.g., group V/groupIII ratio), and/or the like. Such a growth process can modulate aninternal strain in epi-layers and result in a substantially crack-freesemiconductor (e.g., group III nitride) layer. Additionally, it isunderstood that the formation of any combination of one or more layersof the device can include forming one or more patterned surfaces 40 asdescribed herein. Furthermore, one or more metal layers, contacts,and/or additional layers can be formed using any solution. Theheterostructure/device also can be attached to a submount via contactpads using any solution.

It is understood that the fabrication of the emittingdevice/heterostructure can include the deposition and removal of atemporary layer, such as mask layer, the patterning one or more layers,such as the substrate 12 as described herein, the formation of one ormore additional layers not shown, and/or the like. To this extent, apatterned surface 40 can be fabricated using any combination ofdeposition and/or etching. For example, the fabrication can includeselective deposition and/or etching of nanoscale objects, such asnanodots and/or nanorods, and/or micro-scale objects, such asmicro-holes, of the material to form a patterned surface describedherein. Such deposition and/or etching can be used to form periodicand/or non-periodic random patterns.

The patterning of a layer, such as the substrate 12, can be performedusing any solution. For example, the patterning can include defining aset of regions on a top surface of the layer for etching using, forexample, photolithography to apply a photoresist defining the set ofregions, or the like. The set of openings having a desired pattern canbe formed, e.g., by etching in the set of defined regions of the layer.Subsequently, the photoresist can be removed from the surface. Such aprocess can be repeated one or more times to form a complete pattern onthe layer. The patterning of a layer also can include applying (e.g.,depositing) a mask (e.g., silicon dioxide, a carbon based material, orthe like) over a second set of regions on the top surface of the layer.When the pattern also includes a set of openings, the second set ofregions can be entirely distinct from the locations of the set ofopenings. Furthermore, as described herein, the formation of a layer caninclude multiple repetitions of the patterning process. In this case,each repetition can vary from the previous repetition in one or moreaspects. For example, a repetition can include both applying a mask andforming openings on a surface, only forming openings, only applying amask, and/or the like. Additionally, as described herein, the locationsof the masked and/or opening portions for a repetition can be verticallyoffset from the locations of the adjacent repetition.

In an embodiment, the invention provides a method of designing and/orfabricating a circuit that includes one or more of the devices designedand fabricated as described herein. To this extent, FIG. 16 shows anillustrative flow diagram for fabricating a circuit 126 according to anembodiment. Initially, a user can utilize a device design system 110 togenerate a device design 112 for a semiconductor device as describedherein. The device design 112 can comprise program code, which can beused by a device fabrication system 114 to generate a set of physicaldevices 116 according to the features defined by the device design 112.Similarly, the device design 112 can be provided to a circuit designsystem 120 (e.g., as an available component for use in circuits), whicha user can utilize to generate a circuit design 122 (e.g., by connectingone or more inputs and outputs to various devices included in acircuit). The circuit design 122 can comprise program code that includesa device designed as described herein. In any event, the circuit design122 and/or one or more physical devices 116 can be provided to a circuitfabrication system 124, which can generate a physical circuit 126according to the circuit design 122. The physical circuit 126 caninclude one or more devices 116 designed as described herein.

In another embodiment, the invention provides a device design system 110for designing and/or a device fabrication system 114 for fabricating asemiconductor device 116 as described herein. In this case, the system110, 114 can comprise a general purpose computing device, which isprogrammed to implement a method of designing and/or fabricating thesemiconductor device 116 as described herein. Similarly, an embodimentof the invention provides a circuit design system 120 for designingand/or a circuit fabrication system 124 for fabricating a circuit 126that includes at least one device 116 designed and/or fabricated asdescribed herein. In this case, the system 120, 124 can comprise ageneral purpose computing device, which is programmed to implement amethod of designing and/or fabricating the circuit 126 including atleast one semiconductor device 116 as described herein.

In still another embodiment, the invention provides a computer programfixed in at least one computer-readable medium, which when executed,enables a computer system to implement a method of designing and/orfabricating a semiconductor device as described herein. For example, thecomputer program can enable the device design system 110 to generate thedevice design 112 as described herein. To this extent, thecomputer-readable medium includes program code, which implements some orall of a process described herein when executed by the computer system.It is understood that the term “computer-readable medium” comprises oneor more of any type of tangible medium of expression, now known or laterdeveloped, from which a stored copy of the program code can beperceived, reproduced, or otherwise communicated by a computing device.

In another embodiment, the invention provides a method of providing acopy of program code, which implements some or all of a processdescribed herein when executed by a computer system. In this case, acomputer system can process a copy of the program code to generate andtransmit, for reception at a second, distinct location, a set of datasignals that has one or more of its characteristics set and/or changedin such a manner as to encode a copy of the program code in the set ofdata signals. Similarly, an embodiment of the invention provides amethod of acquiring a copy of program code that implements some or allof a process described herein, which includes a computer systemreceiving the set of data signals described herein, and translating theset of data signals into a copy of the computer program fixed in atleast one computer-readable medium. In either case, the set of datasignals can be transmitted/received using any type of communicationslink.

In still another embodiment, the invention provides a method ofgenerating a device design system 110 for designing and/or a devicefabrication system 114 for fabricating a semiconductor device asdescribed herein. In this case, a computer system can be obtained (e.g.,created, maintained, made available, etc.) and one or more componentsfor performing a process described herein can be obtained (e.g.,created, purchased, used, modified, etc.) and deployed to the computersystem. To this extent, the deployment can comprise one or more of: (1)installing program code on a computing device; (2) adding one or morecomputing and/or I/O devices to the computer system; (3) incorporatingand/or modifying the computer system to enable it to perform a processdescribed herein; and/or the like.

The foregoing description of various aspects of the invention has beenpresented for purposes of illustration and description. It is notintended to be exhaustive or to limit the invention to the precise formdisclosed, and obviously, many modifications and variations arepossible. Such modifications and variations that may be apparent to anindividual in the art are included within the scope of the invention asdefined by the accompanying claims.

What is claimed is:
 1. A device comprising: a substrate structure havinga patterned surface, wherein the patterned surface includes a topsurface having a root mean square roughness less than approximately 0.5nanometers and a plurality of openings in the top surface that extendinto an internal portion of the substrate structure, wherein each of theplurality of openings has a diameter between approximately 0.1 micronsand approximately five microns and a depth of at least 0.2 microns; anda first layer directly on the patterned surface of the substratestructure, wherein the first layer is a group III-nitride materialhaving an aluminum concentration of at least seventy percent and havinga thickness at least twice the diameter of the openings, wherein thefirst layer includes: a first sub-layer directly on the patternedsurface of the substrate structure, wherein the first sub-layer has asubstantially flat top surface with a root mean square roughness lessthan approximately 0.5 nanometers and a first plurality of stressreducing regions; and a second sub-layer directly on the top surface ofthe first sub-layer.
 2. The device of claim 1, wherein the patternedsurface is formed using a template layer including the plurality ofopenings located directly on the substrate.
 3. The device of claim 2,further comprising a mask located directly on the substrate in theplurality of openings.
 4. The device of claim 1, wherein the pluralityof openings and the first plurality of stress reducing regions form avertical checkerboard pattern.
 5. The device of claim 1, wherein thesecond sub-layer has a substantially flat top surface with a root meansquare roughness less than approximately 0.5 nanometers and a secondplurality of stress reducing regions, wherein the first layer furtherincludes a third sub-layer directly on the top surface of the secondsub-layer, and wherein each of the plurality of stress reducing regionsand the plurality of openings forms a lateral hexagonal arrangement andwherein the top surfaces are close-packed along a vertical direction toform an overall hexagonal close-packed three dimensional structure. 6.The device of claim 1, wherein the plurality of openings form a lateralhexagonal arrangement.
 7. The device of claim 1, wherein the secondsub-layer includes a top surface with a plurality of openings.
 8. Thedevice of claim 1, further comprising an active layer located on thefirst layer, wherein the device is configured to operate as one of: afield effect transistor, a light emitting device, a light detectingdevice, or a photodetector.
 9. A light emitting device comprising: asubstrate structure having a patterned surface, wherein the patternedsurface includes a top surface having a root mean square roughness lessthan approximately 0.5 nanometers and a plurality of openings formed inthe top surface that extend into an internal portion of the substratestructure, wherein each of the plurality of openings of the substratestructure has a diameter between approximately 0.1 microns andapproximately five microns and a depth of at least 0.2 microns, andwherein the patterned surface further includes a masking structureforming a photonic crystal; a first layer directly on the patternedsurface of the substrate structure, wherein the first layer is a groupIII-nitride material having an aluminum concentration of at leastseventy percent and having a thickness at least twice the diameter ofthe openings of the substrate structure, wherein the first layerincludes: a first sub-layer located directly on the substrate structure,the first sub-layer including a top patterned surface including aplurality of stress reducing regions; and a second sub-layer locateddirectly on the top patterned surface of the first sub-layer; and alight emitting active region located on the first layer.
 10. The deviceof claim 9, wherein the first layer further includes: wherein the secondsub-layer has a substantially flat top surface with a root mean squareroughness less than approximately 0.5 nanometers and a second pluralityof stress reducing regions, wherein the first layer further includes athird sub-layer directly on the top surface of the second sub-layer. 11.The device of claim 10, wherein each of the plurality of stress reducingregions and the plurality of openings of the substrate structure form alateral hexagonal arrangement and wherein the top surfaces areclose-packed along a vertical direction to form an overall hexagonalclose-packed three dimensional structure.
 12. The device of claim 9,wherein the plurality of openings of the substrate structure and theplurality of stress reducing regions are vertically offset to form avertical checkerboard pattern.
 13. The device of claim 9, wherein atleast one of: the diameter of the plurality of openings of the substratestructure, a depth of the plurality of openings of the substratestructure, or a distance between the plurality of openings of thesubstrate structure is less than a wavelength of radiation emitted bythe light emitting device.
 14. The device of claim 9, wherein theplurality of openings of the substrate structure are configured toincrease diffusive light scattering between the substrate structure andthe first layer.
 15. The device of claim 9, wherein at least one of: thediameter of the plurality of openings of the substrate structure, or adistance between the plurality of openings of the substrate structurevaries in a lateral direction to provide a graded refractive index ofthe patterned surface.
 16. A device comprising: a first layer having apatterned surface, wherein the patterned surface includes a top surfacehaving a root mean square roughness less than approximately 0.5nanometers and a first plurality of stress reducing regions on the topsurface, wherein each of the first plurality of stress reducing regionshas a diameter between approximately 0.1 microns and approximately fivemicrons, wherein the first plurality of stress reducing regions areseparated by a distance less than or equal to the diameter, and whereinthe first plurality of stress reducing regions form a lateral hexagonalarrangement; and a second layer directly on the patterned surface of thefirst layer, wherein the second layer is a group III-nitride materialhaving an aluminum concentration of at least seventy percent and havinga thickness at least twice the diameter of the stress reducing regions.17. The device of claim 16, wherein a top surface of the second layerhas a root mean square roughness less than approximately 0.5 nanometersand a second plurality of stress reducing regions, and wherein thedevice further includes a third layer directly on the top surface of thesecond layer, wherein the third layer is a group III-nitride materialhaving an aluminum concentration of at least seventy percent and havinga thickness at least twice the diameter of the stress reducing regions.18. The device of claim 17, wherein the first and second pluralities ofstress reducing regions are vertically offset to form a verticalcheckerboard pattern.
 19. The device of claim 16, wherein the firstlayer comprises a substrate structure including a substrate and atemplate layer located directly on the substrate, wherein the firstplurality of stress reducing regions comprise openings in the templatelayer.
 20. The device of claim 19, further comprising a mask locateddirectly on the substrate in the first plurality of stress reducingregions.